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Several symmetry operators may be applied to the same molecule, these constitute a point gr.oup. A group is a well defined concept in mathematics (see Sec. 2.7.3.1). The name point group indicates that at least one point (the center of mass) remains unmoved, when the symmetry operations are carried out. There is a limited number of point groups of molecules. Crystallographs count 32 point groups, since only operators related to 1-, 2-, 3-, 4- and 6-fold symmetry axes may be applied to parallelepipeds filling the space of crystals. In molecular spectroscopy, 5, 7-, and 8-fold symmetry axes also exist, which increases the number of point groups in this field. Point groups are usually characterized by symbols, introduced by Schoenflies in 1891 (Schoenflies, 1891, 1923). Group theory was first applied to molecular vibrations by Brester (1 923) and Wigner (193 l), see also Rosenthal and Murphy (1936). IUPAC recommendations have been published by Mulliken ( 1955), a revised recommendation is in preparation (Sullivan, 1994). IUPAC as well as IUPAP recommend the use of the Schoenflies notation, whereas the International Union of Crystallography uses the 'international' notation, introduced by Hermann ( 1 928) and Mauguin (1 93 I ) , see Hahn (1987). The Schoenflies symbols representing the point groups of molecules are defined as follows. All groups contain the identity operator. 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